Enthalpy Change Equation:
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Enthalpy change (ΔH) is the heat energy change measured under conditions of constant pressure. It's a fundamental concept in thermodynamics that helps predict whether a chemical reaction will be exothermic (releases heat) or endothermic (absorbs heat).
The calculator uses the enthalpy change equation:
Where:
Explanation: Breaking bonds requires energy (endothermic, positive sign), while forming bonds releases energy (exothermic, negative sign). The net change determines if the overall reaction is exothermic or endothermic.
Details: Calculating enthalpy changes helps predict reaction feasibility, design chemical processes, and understand energy requirements in industrial applications.
Tips: Enter the total bond energies for broken and formed bonds in kJ/mol. Values must be positive numbers. The calculator will compute the enthalpy change.
Q1: What does a negative ΔH value mean?
A: A negative ΔH indicates an exothermic reaction where more energy is released in bond formation than is required for bond breaking.
Q2: What does a positive ΔH value mean?
A: A positive ΔH indicates an endothermic reaction where more energy is required for bond breaking than is released in bond formation.
Q3: Where can I find bond energies?
A: Standard bond energies are available in chemistry reference tables. These are average values measured under standard conditions.
Q4: Are there limitations to this calculation?
A: Yes, bond energies are averages and don't account for molecular environment. For precise calculations, use Hess's Law with formation enthalpies.
Q5: How does this relate to Gibbs free energy?
A: While ΔH measures heat change, Gibbs free energy (ΔG = ΔH - TΔS) determines reaction spontaneity by also considering entropy (ΔS) and temperature (T).